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Article:

Successful Job Transitions, III: Starting a New Job

It's still OK to be antisocial

Don't be inviting everyone you meet to connect with you on social networking sites. Besides the potential pitfalls of wasting time and unnecessary personal exposure, now is the time for building real life, bricks and mortar relationships that are defined by work and not unconnected interests.

If you want to fit in, work is the place for that, not the Internet.